Recent unexpected occurrences of stress corrosion cracking scc with 174 ph structural components indicated a need for improved characterization of the alloy and application of more advanced analytical procedures for reliably predicting structural performance. The precipitationhardening stainless steel 17 4 ph is widely used for oilfield components tubing hangers and valve stems due to its favourable combination of high strength and corrosion resistance. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Chloride stress corrosion cracking of precipitation hardening s. Cracking due to cu and ni segregation in a 174 ph stainless. In general, the corrosion resistance of ati 174 alloy is superior to that of the hardenable 400 series stainless steels. Stainless shapes is a proud 17 4 ph stainless steel supplier. This steel is well indicated for making medical, surgical and dental instruments as well as other products with similar requirements. Consequently, in applications in which chloride stress corrosion cracking.
For example, the highest k ic value recorded was 1 ksiyin. Ph 148 mo, 155 ph, 174 ph, a286, almar 362, and upitemp 212 stainless steels were highly resistant to stress corrosion cracking. The problem of corrosion the special case of stainless steel types of corrosion general corrosion localized corrosion intergranular corrosion pitting corrosion crevice corrosion galvanic corrosion stress corrosion cracking factors affecting corrosion corrosion testing intergranular corrosion pitting and crevice corrosion stress corrosion cracking. In addition, three 174 ph materials were studied in terms of microstructure, mechanical properties and susceptibility to sulfide stress cracking. Sulphide stress cracking of 174 ph for applications in oilfield components. These corrosion data are mainly based on results of general corrosion laboratory tests, carried out with pure chemicals and water solutions nearly saturated with air the corrosion rate can be quite different if the solution is free from oxygen all concentrations are given in weight% and the solvent is water if nothing else is shown.
The consequences of stress corrosion failures may be serious, even leading to loss of an aircraft. Corrosion of carbon steel digesters has been a perennial design problem. On the other hand, some steels with lower fracture toughness were immune to stress corrosion cracking. As with other precipitation hardening stainless steels, ati 174 precipitation hardening stainless steel is more susceptible to stress corrosion cracking at peak strength. Because of the simplicity of fabrication, even lowalloy carbon steels can often be replaced economically with armco 174 ph stainless steel.
Without age hardening, this material is more susceptible to stress corrosion cracking. Galvanic corrosion stress corrosion cracking factors affecting corrosion corrosion testing intergranular corrosion pitting and crevice corrosion stress corrosion cracking corrosion in atmospheres importance of cleaning and passivating. Chloride stress corrosion cracking the greatest corrosion advantage for duplex stainless steels is their improved resistance to cscc when compared to the austenitic grades. Per msfcspec522, 17 4 ph is a table ii material with only moderate resistance to stress corrosion cracking. On the hardness criterion for stress corrosion cracking resistance of 17 4 ph stainless steel. Also, in the h900 condition, the material becomes more susceptible to environmentally assisted cracking, such as he and stress corrosion cracking scc. Alloy 17 4ph in the solutionannealed condition condition a should not generally be put in service.
Allowable stress values for 174 ph stainless steel h1150. Alloy 174 ph 17cr4ni4cu is an example of this type alloy. On the hardness criterion for stress corrosion cracking resistance of 174 ph stainless steel. The preceding discussion has focused on the dependency of scc propagation on various system parameters, and the prediction capability for these dependencies is based on an understanding of the mechanism of crack propagation. Hardenable stainless steels, like other highstrength steels, are susceptible to cracking under the combined influence of tensile stress and corrosion, depending on the severity of the stress, the nature of the media and to a large extent, on their hardness.
Stress corrosion cracking of hardenable stainless steels. Selection of metallic materials for stress corrosion cracking resistance in sodium chloride environments 1. Stress corrosion cracking scc is a common issue with many specialty alloys. As with other precipitation hardening alloys, al 17 4 precipitation hardening alloy is more susceptible to stress corrosion cracking at peak strength. Request pdf stress corrosion cracking in 174ph and 177ph stainless steels in nacl and naoh 20% a 90c one of the problems that affects to the electric industry is the not programmed. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will. Corrosion resistant guide for 174 ph stainless steel 10 cr 20 issue 798 fluid 174 ph stainless steel 75f 150f acetic acid 20% a b acetic acid 50% a b acetone a a air a a aluminum chloride d d aluminum fluoride d d aluminum sulfate c ammoniaanhydrous a a ammoniumchloride d d ammonium hydroxide 10% a a ammonium hydroxide. Sco with 174 ph structural components indicated a need for improved. Terrible to machine, but strong and has excellent corrosion resistance. Stabilized to prevent intergranular corrosion as welded. In context of acceptability of 174 ph in sour service, an literature survey of complex metallurgy of this grade was done following a mechanical rupture in service.
In context of acceptability of 17 4 ph in sour service, an literature survey of complex metallurgy of this grade was done following a mechanical rupture in service. For stress corrosion cracking, 160f is considered an elevated temp. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Prediction of stress corrosion cracking scc in boiling water reactor bwr components. Uses for 174 include components which require high hardness andor corrosion resistance at temperatures of up to 600 f 316 c. Only the 25% nickel grades have similar cscc resistance. This document defines the design criteria that shall be used for the selection of metallic materials in order to prevent failure due to stress corrosion cracking. Recent unexpected occurrences of stresscorrosion cracking scc with 174 ph structural components indicated a need for improved characterization of the alloy and application of more advanced analytical procedures for reliably predicting structural performance. Technical information stainless steel precipitation. Precipitation hardening stainless steels alloys, properties. Accordingly, the purpose of the present studies was to establish systematically. Alloy 174 ph withstands corrosive attacks better than any of the standard hardenable stainless steels and is comparable to alloy 304 in most media. Condition h900 gives the higher mechanical strength and hardness, but the minimum toughness and ductility.
National association of corrosion engineers, standard mr0175. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. Stress corrosion cracking properties of 17 4 ph steel. Stress corrosion behavior of selected types of stainless. Physical properties condition a density linear coefficient of. The precipitationhardening stainless steel 174 ph is widely used for oilfield components tubing hangers and valve stems due to its favourable combination of high strength and corrosion resistance. Specific applications for 174 include the petroleum and chemical industries, as well as use in aircraft parts. Effect of heat treatment anomaly on the stress corrosion. Issf martensitic stainless steels 10 oil and gas recovery.
Pdf cracking due to cu and ni segregation in a 174 ph stainless. Stress corrosion cracking behaviour of 174 ph stainless steel. Failure of 174 ph stainless steel components in offshore. The alloy is subject to brittle fractures and more sensitive to chloride stress corrosion cracking than the aged material. In many cases, problems with stress corrosion cracking scc can be solved by selecting a suitable material. Compared to other ph alloys, it requires a simple heat treatment to produce a wide range of properties, including its high strength. Numerous investigations conducted in the past decades outlined its corrosion performance and confirmed its cracking propensity. Although the general corrosion resistance of nitronic 60 is not quite as good as type 316, it does offer better chloride pitting resistance, stress corrosion cracking resistance, and crevice corrosion resistance than type 316 in laboratory conditions. High strength is maintained to approximately 600 degrees fahrenheit 316 degrees celsius. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries.
This is a type of deterioration which can be linked to corrosion and corrosion control processes. Effect of aging temperature on stress corrosion cracking of 174. Precipitation hardening will produce surface oxidation. Sep 18, 2017 fracture mechanicsbased testing was used to quantify the stress corrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in full. Recent unexpected occurrences of stresscorrosion cracking. The oxidation resistance of the al 174 alloy is superior to that of 12 percent chromium alloys like type 410, but slightly inferior to that of type 430. In this chapter, three cases of failure analysis of 174 ph steel in the oil and gas industry are presented. In oil and gas production systems containing hydrogen sulphide h 2 s, however, this material is highly susceptible to sulphide stress cracking. Corrosion resistance is similar to that found in grade 304 stainless steel. Stress corrosion cracking resistance is also quite good. Condition a material has been used successfully in numerous applications. Data obtained via use of the rising step load test method, with samples in the h950 condition tested in 3. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. This is an attractive characteristic to aging the 174 ph stainless steel to the h1150m condition since in sour service applications nace mr0175 maintaing low hardness is a critical defense against hydrogen stress corrosion cracking.
Download citation effect of aging temperature on stress corrosion cracking of 174 ph stainless steel in wet h2s environment the effect of aging. Fatigue and corrosion fatigue pose longterm threats to the reliability and lifecycle costs of advanced highstrength ship structures. In warm chloride environments, 174 ph is susceptible to pitting and crevice corrosion. Better stress corrosion cracking resistance comes with higher ageing temperatures. A very good alloy to try would be s20910 or nitronic 50. Alloy 174ph has corrosion resistance comparable to 304l in some chemical, dairy, food, paper and petroleum applications. Type 17 4 ph ams 5604 is the most widely used of all precipitationhardening steels. Stress corrosion cracking scc is particularly important for aerospace vehicles, since it occurs, or can occur, in all major alloy systems used in their construction. This material has good resistance to stress corrosion cracking in the low strength conditions. Fundamental considerations of fatigue, stress corrosion.
Stress corrosion cracking behaviour of 174 ph stainless steel weldments at opencircuit potentials. Carpenter technologys cartech custom 465 stainless steel uns s46500 is a premium double vacuummelted, martensitic, agehardenable alloy that offers a unique combination of high strength, toughness and corrosion resistance. Because of the simplicity of fabrication, even lowalloy carbon steels can often be replaced economically with armco 17 4 ph stainless steel. In general, the fracture toughness and stress corrosion resistance. There is a growing acceptance of the term scc to co\er both mechanisms. Mar 26, 2019 the paper examines the effect of deviation in heat treatment due to sudden furnace breakdown and its impact on the stress corrosion cracking scc susceptibility of 17 4 ph stainless steel used in pyro bolts for solid rocket boosters.
Stress corrosion cracking and hydrogen embrittlement of high. In such media cracking may occur in the standard grades under stress at hardnesses of rockwell c24, in severe marine atmospheres at c40 and in industrial atmospheres at c45. Alloy 17 4ph has corrosion resistance comparable to 304l in some chemical, dairy, food, paper and petroleum applications. The main impurities 99 stress corrosion cracking of 174ph steel in steam turbine environments that have been found include sodium chloride nacl, sodium hydroxide naoh and sodium sulphate na2s04. February 190 stresscorrosion properties s highstrength. Recent unexpected occurrences of stress corrosion cracking scc with 17 4 ph structural components indicated a need for improved characterization of the alloy and application of more advanced analytical procedures for reliably predicting structural performance. Chloride stress corrosion cracking in austenitic stainless. Stress corrosion cracking stress corrosion cracking scc is the growth of cracks under the combined influences of sustained tensile stress and a seawater.
Alloy 174 ph precipitation hardening sandmeyer steel. The precipitationhardening stainless steel 174 ph is widely used for. All three heat treatments given the 174 ph stainless steel were outstanding in. Stresscorrosion cracking properties of 174 ph steel astm. Its relatively inexpensive to alternatives and has great strength. If there are potential risks of stress corrosion cracking, the higher aging temperatures then must be selected over 1022f 550c, preferably 1094f 590c. In addition, three 17 4 ph materials were studied in terms of microstructure, mechanical properties and susceptibility to sulfide stress cracking. The failure of highstrength fasteners in aerospace equipment as a result of scc or hsc occurs infrequently and almost always unexpectedly. On the hardness criterion for stress corrosion cracking.
Sulphide stress cracking of 174 ph for applications in. Exposure of 174 ph stainless steel to a simulated hwctr environment indicates that this alloy is susceptible to stresscorrosion cracking when aged at 900 deg f, but is not susceptible when aged at 1100 deg f. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. The interaction of corrosion fatigue and stresscorrosion. Corrosion resistance alloy 174 ph withstands corrosive attacks better than any of the standard hardenable stainless steels and is comparable to alloy 304 in most media. When aged at 550c or higher, 174 ph is highly resistant to stress corrosion cracking. The risk of stress corrosion cracking scc can be minimized through plant and equipment design. It is especially important to avoid any mechanical tensile stress concentration, which will occur at sharp edges and notches. As with other precipitation hardening stainless steels, ati 174 precipitation hardening stainless steel is more susceptible to stress corrosion cracking at peak. The scc susceptibility of the alloy was examined in 3. Practical immunity to chloride stress corrosion cracking. Exposure of 17 4 ph stainless steel to a simulated hwctr environment indicates that this alloy is susceptible to stress corrosion cracking when aged at 900 deg f, but is not susceptible when aged at 1100 deg f. This is because type 17 4 ph stainless steel has a higher yield pressure than carbon steel.
New grades most of them proprietary more resistant to stress corrosion cracking scc and sulfide stress cracking ssc are now under development and are. Alloy 174ph in the solutionannealed condition condition a should not generally be put in service. The use of type 17 4 ph stainless steel, which has a high resistance to corrosion, has been of great significant value in the paper industry. Prediction of stress corrosion cracking scc in nuclear. Chloride stress corrosion cracking in austenitic stainless steel. Overaging aging beyond the peak strength condition improves resistance to stress corrosion cracking.
The hardness and tensile properties fall within the range of. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Effect of reversed austenite on the stress corrosion. As with other precipitation hardening stainless steels, ati 174 precipitation hardening stainless steel is more susceptible to stress corrosion cracking. The problem of stress corrosion cracking scc, which causes sudden failure of metals and other materials subjected to stress in corrosive environments, has a significant impact on a number of sectors including the oil and gas industries and nuclear power production. A study has been conducted investigating the effect of reversed austenite on the stress corrosion cracking property of a chemically modified 174ph with specially designed twostep tempering in a simulated geothermal environment. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Stress corrosion cracking in 174ph and 177ph stainless. Sulphide stress cracking of 174 ph for applications in oilfield components article in materials science and technology 3316.
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